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VIDEO (Alkane derived compounds)

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ALCOHOL
All alcohols contain the -OH group, for example ethanol. Alcohol has similar chemical properties. All ethers contain an -O- group, for example dimethylters. Ether has similar chemical properties. Groups such as -OH and -O- are replaced in hydrocarbon chains called functional groups. They dominate chemical molecules and provide characteristic properties.
The hydrocarbon chain is the symbol of R. The naming of organic compounds is divided into two, named naming according to IUPAC (systematic name) and trivial naming (common name).
Naming according to IUPAC is established by IUPAC (International Union and Pure Applied Chemistry), whereas trivial naming is a naming system that has been known before the establishment of the naming system according to the IUPAC.
The trivial name is more popular in industry and commerce because of its easy mention.Nomenclature of Alcohol (alkanol) IUPAC:
Alcohol is a derived compound of alkanes whose anto H is replaced by the -OH group.
1) Select the longest carbon chain containing the -OH group as the main chain and name it as the alkane by changing the suffix "a" to the end of "ol"2) Do numbering by giving the lowest possible number on the carbon atom that binds the -OH group.3) If there is a branch, the naming is done like the alkana nomenclature.4) The order of writing of his name is: branch number and branch name (if any) - number of cluster -OH - name of main chain.
Nomenclature of alcoholTrivial nicknames:
Select the longest carbon chain containing the -OH group as the main chain. Name the chain with the name alkyl, that is by replacing the suffix "ana" to "it". Then follow the name with the word "alcohol".
CH3OH: methyl alcoholCH3CH2OH: ethyl alcohol 

ETHER
Ether IUPAC nomenclature:
The method of naming according to IUPAC is to see that the ether is an alkoxy (-O-R ') group attached to an alkane. Therefore, the ether is also called alkoxyalkane. The location of the alkoxy group in the alkane is numbered as to the numbering of the alkyl group from a branched alkane.Trivially nicknames:
If the ether is regarded as an -O group which binds two alkyl (R) groups with the structure: R -O-R ', the method of naming is as follows.

1) Ether having an alkyl group R equal to R 'is called symmetric ether and its name is called dialkyl ether.
2) Ether having R group is not equal to R 'the naming is: alkyl (R) - alkyl (R') - ether, taking into account the alphabetical order.


KETONE
IUPAC Keton Name
The IUPAC nomenclature of ketones simply replaces the suffix -a in alkanes with -on for ketones with the same number of carbon chains. For example, if in alkanes there is propane, then in ketones there are propanones, each of which has the same number of carbon chains, ie three. Ketones are one of carbonyl compounds, which means having carbonyl (C = O) groups in their structure. Since the general formula of the ketone is R (C = O) R ', the shortest ketone is propanone.Propanone
The position number of the carbonyl group in the carbon chain is written on the front. If there are other functional groups, then the numbering starts from the C end atoms adjacent to the carbonyl group. Example:Trivial Keton Name
The naming of the trivial name for the ketone uses the same way for the ether, ie by mentioning the groups attached to the carbonyl group, followed by the mention of the ketone.Acetone







ALDEHYD

Like other organic compounds, aldehydes have IUPAC and trivial (general) nomenclature. Here is the discussion of the nomenclature of aldehydes: 
Name of IUPAC Aldehyde
Simply put, the IUPAC nomenclature for the aldehyde compound is by changing the suffix -a in alkanes with -al for aldehydes of the same carbon chain length. For example, if in alkanes there are ethane compounds, then in aldehydes of the same carbon chain length (2 carbon atoms) is called ethanal.
There are also aldehydes having substituted H atoms with other atoms. Then the substituent is numbered in the order of the carbon atom that binds it.Bromo hydroxy pentanalName of Trivial Aldehyde
The trivial name for the aldehyde group is highly dependent of the aldehyde oxidation-derived compounds. For example, CH 3 COOH can be obtained from the oxidation of CH3CHO compounds. Since CH3COOH is called acetic acid, CH3CHO is called acetaldehyde. In the same way, it can be seen that benzoic acid is derived from the oxidation of benzaldehyde.
Substitution of H atoms is also prescribed for the trivial name. For the name of the trivial aldehyde, the substituent is numbered with the symbols α, β, γ and so on. Example:


























asam valerat, valeraldehida


CARBOXYLIC ACIDSCarboxylic acids and esters are functional group isomers having the same molecular formula but different functional groups. The functional groups of carboxylic acids are carboxyl groups -COOH, and in the carboalkoxy group ester (-COOR).
Carboxylic acid or alkanoic acid is an alkane-derived carbon compound containing a carboxyl group -COOH group attached to an alkyl group R. The COOH group is complex because it comprises an oxygen-hydroxyl group such as an alcohol and a carbonyl -CO group as well as an aldehyde And ketones.Carboxylic acid may contain more than one -COOH group, ie an alkanoid acid containing 2 -COOH groups, an alkanatrioic acid containing 3 -COOH groups, and so on.
The simplest carboxylic acid is methanoic acid and most commonly found in daily activities is acetic acid (ethanoic acid / vinegar)The general formula of carboxylic acids is expressed asCnH2nO2The carboxylic acid structure can also be written as a group -COOH bound to an alkyl group R.

    
R-COOH R is an alkyl group

NAME OF CARBOKSILATE ACID
There are two nomenclature carboxylic acids, namely the IUPAC nomenclature and the common name (trivial).1. IUPAC nomenclatureSelect the longest carbon chain containing the -COOH group and be named after the alkane by replacing the "a" suffix with the "oat" suffix and plus the "acid" prefix. If the main chain binds the alkyl group as a branch, the numbering starts from the -COOH group.
2. Trivial nicknamesThere is a common name that is better known because the name has been used before the IUPAC.HCOOH Metanoic acid Formic acid (formica = ant)CH3COOH Ethanoic acid Acetic acid (acetamin = vinegar)C2H5COOH Propanoic acid Propionic acid (protopion = first fat)


ESTER
Just like other alkane derivatives, esters have rules in the IUPAC nomenclature:
  1. Cluster -COOR in separate ester in its naming, which is divided over -COO and -R
  2. The -COO group is an alkanoate group, while the -R group is an alkyl group
  3. The R-group is always near oxygen (O) at -COO
  4. The next group -COO (not -OR; alkyl) is a branch chain, and, its C atom joins the C atom at -COO (see figure!)
  5. The naming is alkyl + alkanoate. Thus, the alkyl group just mentioned the alkanoate group
  6. All clusters -COOR get into the main chain
  7. In the IUPAC ester naming, if there is a branch, -COO always gets the number 1 and goes in the main chain 
The trivial name of ester
The usual name is alkyl alkyl ester, just like ether  Alkyl alkyl at number 1 is not sorted alphabeticall. In a common name, there must be an O atom in the middle

Komentar

  1. Explain examples of alkanes and ether in daily life and benefits?

    BalasHapus
    Balasan
    1. Benefits of alkanes
      Solvents: Different types of hydrocarbons, such as Petroleum ether and naphtha, are used as industrial solvents or dry cleaning.
      Hydrogen Source: Natural gas and petroleum gas are sources of hydrogen in the industry, such as the ammonia industry and fertilizers.
      Raw materials for other organic compounds: Petroleum and natural gas are the main raw materials for the synthesis of various organic compounds such as alcohol, vinegar and others.
      Fuel: eg LPG, kerosene, gasoline, and diesel fuel.
      Lubricants: Lubricants are high temperature alkanes (the number of carbon atoms per molecule is large, for example: C18H38.
      Industrial raw materials: Various industrial products such as plastics, detergents, synthetic rubbers, crude oil and liniment, made from petroleum and natural gas. Industries that process petroleum and natural gas is called petrochemical industry (petroleum = petroleum).

      Some ether benefit is ether used as a solvent. Diethyl ether is used as an anesthetic in the operation. Methyl tert-butyl ether (MTBE) is used to increase the octane number of gasoline.

      Hapus
  2. Explain the benefits of esters and ester weakness

    BalasHapus
    Balasan
    1. The benefits of ester is
      -As essence on food and drink. Some esters have an aroma of fruits such as apples (methyl butyrate), banana aroma (amyl acetate), and pineapple (ethyl butyrate) scent.
      -Beeswax, ester mixtures such as C25H51COO - C30H61, and caurnauba waxes are used in car paint and upholstery and furniture.
      -Flats and oils are important esters found in our diet.
      -Esters such as aspirin and methyl salicylate are used in medicine as an analgesic and anti-inflammatory agent. Methyl salicylate, also called wintergeen oil, is the main ingredient of wintergeen flavor. Ethyl acetate is used as a nail / nail polish remover.
      -As a matter of making soap.
      -As a matter of making butter.

      The negative impact of the ester is that it can cause genetic abnormalities such as cancer, cell aging, and other organ damage.

      Hapus
  3. Alcohol consists of 3, there are primary, secondary, and tertiary alcohols. please explain

    BalasHapus
    Balasan
    1. The primary alcohol is the alcohol with the -OH group attached to the primary C atom, ie the C atom binding 1 other C atom. Example: butanol and propanol
      Secondary alcohols are alcohols with -OH groups attached to secondary C atoms, ie C atoms binding 2 other C atoms. Example: 2-butanol and 2-propanol
      Tertiary alcohols are alcohols with an -OH group attached to a tertiary C atom, that is, C atoms binding 3 other C atoms. Example: 2-methyl 2-propanol

      Hapus
  4. Why you choose this topic?

    BalasHapus
    Balasan
    1. I just picked at random, and maybe because this is one of my favorite lessons

      Hapus
  5. Give an idea of the alcohol of daily life?

    BalasHapus
    Balasan
    1. Alcohol can help reduce high blood pressure if taken in a fairly low dose. How it works is to clean up the deposits of fat contained in the arteries. It also can reduce blood clotting. This can also reduce the risk of heart attack. Remember to not consume alcohol excessively. Because, although many benefits, if consumed in excess will actually cause various diseases.

      Minimizing Stroke Risk
      The type of ischemic stroke becomes one of the most common types of strokes to attack. This type of stroke is known to be caused by a blockage in the blood vessels that lead to the brain organ. While other types of stroke is a hemorrhagic stroke that occurs due to blood seeping or leaking and out of the blood vessels in the brain. Of course as long as the risk of stroke can be prevented and minimized, efforts that can be done should be tried and one of them by taking alcohol.

      Helps Improve Sleep Quality
      Benefits of alcohol in daily life that can help improve the quality of night sleep. Surely these benefits can help you who often experience trouble sleeping or insomnia. This is nothing but the drowsiness effect of alcohol on the human body. To get this benefit can be tried by consuming alcohol in accordance with the dosage recommended by the doctor. Known dose is safe and recommended to help improve the quality of sleep is not more than one glass.

      Improving Body Warmth
      Of course this benefit will you get automatically when consuming alcohol, the body will feel warm. Alcohol has long been used in many European countries with high winter intensity to warm the body.

      Hapus

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